由磁化纳米腔等离子体诱导的光磁效应
Sai Duan1,2, Zilvinas Rinkevicius2,3,4, Guangjun Tian5
1Hefei National Laboratory for Physical Sciences at the Microscale, Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China , Hefei , 230026 Anhui , People's Republic of China.
Journal of the American Chemical Society
|August 21, 2019
概括
在纳米腔中产生一种新的光磁效应,产生强大的磁场,使分子旋转转变得可控. 这一突破促进了特定分子激发状态的产生, 并探索了新的光物质相互作用.
科学领域:
- 质子学和纳米光学
- 量子化学
- 分子光谱学
背景情况:
- 在纳米空隙中封闭的等离子场提供了独特的光物质相互作用的可能性.
- 使用常规方法激活分子中的自旋禁止过渡是具有挑战性的.
研究的目的:
- 引入并研究由纳米腔等离子体驱动的新光磁效应.
- 通过这种效应来证明旋转禁止分子过渡的激活.
- 探索不同自旋倍率的分子激发状态的控制潜力.
主要方法:
- 在纳米空洞内理论建模等离子体场.
- 模拟分子转换的光磁效应的第一原则计算.
- 作为一个模型系统,研究C60分子中的转换.
主要成果:
- 在纳米腔中高度封闭的等离子场会诱导显著的动态磁场.
- 这种动态磁场可以直接激活分子中的自旋禁止过渡 (例如单片到三片).
- 在特定条件下,激活的自旋禁止转换的强度可以超过允许的单片到单片转换 (与分子大小相匹配的等离子分布).
结论:
- 拟议的光磁效应为设计具有定制自旋多重性的分子激发状态提供了一条新途径.
- 这项研究引入了光与物质相互作用的突破性概念,
相关概念视频
Colors and Magnetism
14.0K
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
14.0K
Magnetism
8.4K
Magnets are commonly found in everyday objects, such as toys, hangers, elevators, doorbells, and computer devices. Experimentation on these magnets shows that all magnets have two poles: one is labeled north (N) and the other south (S). Magnetic poles repel if they are alike and attract if unlike. Moreover, both poles of a magnet attract unmagnetized pieces of iron.
An individual magnetic pole cannot be isolated. No matter how small, every piece of a magnet contains a north pole and a south...
An individual magnetic pole cannot be isolated. No matter how small, every piece of a magnet contains a north pole and a south...
8.4K
Magnetic Flux
4.5K
The magnetic flux measures the number of magnetic field lines passing through a given surface area. The SI unit for magnetic flux is the weber (Wb). Magnetic flux is a scalar quantity. It depends on three factors: the strength of the magnetic field B, the area through which the field lines pass, and the relative orientation of the field with the surface area.
Suppose a surface is divided into elements of area dA. For each element, the component of the magnetic field that is normal to the...
Suppose a surface is divided into elements of area dA. For each element, the component of the magnetic field that is normal to the...
4.5K
Magnetic Damping
1.0K
Eddy currents can produce significant drag on motion, called magnetic damping. For instance, when a metallic pendulum bob swings between the poles of a strong magnet, significant drag acts on the bob as it enters and leaves the field, quickly damping the motion.
If, however, the bob is a slotted metal plate, the magnet produces a much smaller effect. When a slotted metal plate enters the field, an emf is induced by the change in flux; however, it is less effective because the slots limit the...
If, however, the bob is a slotted metal plate, the magnet produces a much smaller effect. When a slotted metal plate enters the field, an emf is induced by the change in flux; however, it is less effective because the slots limit the...
1.0K
Magnetic Declination
413
Magnetic declination is the angle between true north, which aligns with the Earth's rotational axis, and magnetic north, which follows the direction of the Earth's magnetic field. This discrepancy exists because the magnetic poles do not coincide with the geographic poles. The value of magnetic declination depends on the observer's location on Earth and is subject to changes over time due to the dynamic nature of the Earth's magnetic field.The declination is called eastern when magnetic north...
413
Magnetic Fields
7.1K
A moving charge or a current creates a magnetic field in the surrounding space, in addition to its electric field. The magnetic field exerts a force on any other moving charge or current that is present in the field. Like an electric field, the magnetic field is also a vector field. At any position, the direction of the magnetic field is defined as the direction in which the north pole of a compass needle points.
A magnetic field is defined by the force that a charged particle experiences...
A magnetic field is defined by the force that a charged particle experiences...
7.1K


