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相关概念视频

Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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Polymers02:34

Polymers

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Protein-protein Interfaces02:04

Protein-protein Interfaces

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Many proteins form complexes to carry out their functions, making protein-protein interactions (PPIs) essential for an organism's survival. Most PPIs are stabilized by numerous weak noncovalent chemical forces. The physical shape of the interfaces determines the way two proteins interact. Many globular proteins have closely-matching shapes on their surfaces, which form a large number of weak bonds. Additionally, many PPIs occur between two helices or between a surface cleft and a...
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Protein-Protein Interfaces02:04

Protein-Protein Interfaces

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Frequency-dependent Selection01:21

Frequency-dependent Selection

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When the fitness of a trait is influenced by how common it is (i.e., its frequency) relative to different traits within a population, this is referred to as frequency-dependent selection. Frequency-dependent selection may occur between species or within a single species. This type of selection can either be positive—with more common phenotypes having higher fitness—or negative, with rarer phenotypes conferring increased fitness.
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Aggregates Classification01:29

Aggregates Classification

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Aggregate classification is generally based on its size, petrographic characteristics, weight, and source. Size classification ranges from coarse to fine aggregates, defined by the size of the particles. Coarse aggregates are particles that do not pass through ASTM sieve No. 4, and aggregates that pass through the sieve are fine aggregates.
Petrographic classification groups aggregates based on common mineralogical characteristics. Some of the common mineral groups found in aggregates are...
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Multiscale Structures Aggregated by Imprinted Nanofibers for Functional Surfaces
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在玻璃刷聚合物纳米纤维中因界面依赖聚合诱导的延迟光

Christopher M Tonge1, Zachary M Hudson1

  • 1Department of Chemistry , The University of British Columbia , 2036 Main Mall , Vancouver , British Columbia V6T 1Z1 , Canada.

Journal of the American Chemical Society
|August 24, 2019
PubMed
概括

玻璃刷纳米纤维提供了一种控制光电子聚合物之间的相互作用的方法. 这可以调整先进材料的热激活延迟光 (TADF) 特性.

科学领域:

  • 聚合物化学
  • 材料科学
  • 光电子产品

背景情况:

  • 玻璃刷共聚物使得具有固有的纳米分离的多部分纳米材料的制造成为可能.
  • 控制不同聚合物之间的接口对于光电子设备的性能至关重要.

研究的目的:

  • 合成和描述瓶纳米纤维使用基于阿克里丁和三的供体/接受体对.
  • 研究瓶形态对通过空间的电荷转移 (TSCT) 和热激活的延迟光 (TADF) 特性的影响.
  • 证明对光电子应用的聚合物相互作用的控制能力.

主要方法:

  • 具有不同供体和受体域形态 (随机,微臂,块) 的瓶纳米纤维的合成.
  • 包括TSCT和TADF在内的材料特性.
  • 薄膜的制造和纤维聚合效应的研究

主要成果:

  • 在瓶刷纳米纤维中实现对捐赠器和接受器域安排的控制.
  • 已证明的纳米纤维具有强大的TSCT TADF,在聚合时可切换的TSCT TADF或保存的单个组件特性.
  • 展示了不同光电子聚合物之间促进或抑制相互作用的能力.

结论:

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  • 瓶刷策略为多元组件聚合物系统的设计界面提供了一种多功能途径.
  • 这种方法可以通过操纵聚合物相互作用来精确控制光电子特性.
  • 在半导体聚合物混合物中提供最大化或最小化捐赠者接受器相互作用的方便方法.