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Hydrogenation06:06

Hydrogenation

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Source: Vy M. Dong and Zhiwei Chen, Department of Chemistry, University of California, Irvine, CA
This experiment will demonstrate the hydrogenation of chalcone as an example of an alkene hydrogenation reaction (Figure 1). In this experiment, palladium on carbon (Pd/C) will be used as a heterogeneous catalyst for the process. A balloon will be used to supply the hydrogen atmosphere.
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Source: Deepika Das, Tamara M. Powers, Department of Chemistry, Texas A&M University
Bioinorganic chemistry is the field of study that investigates the role that metals play in biology. Approximately half of all proteins contain metals and it is estimated that up to one third of all proteins rely on metal-containing active sites to function. Proteins that feature metals, called metalloproteins, play a vital role in a variety of cell functions that are necessary for life. Metalloproteins...
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Efficient solar-hydrogen production has recently been realized on functionalized semiconductor-electrocatalyst systems in a photoelectrochemical half-cell in microgravity environment at the Bremen Drop Tower. Here, we report the experimental procedures for manufacturing the semiconductor-electrocatalyst device, details of the experimental set-up in the drop capsule and the experimental sequence during free...
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Hydrogen Bonds00:26

Hydrogen Bonds

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Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
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The preparation of SNS pincer cobalt(II) model complexes of liver alcohol dehydrogenase is presented here. The complexes can be prepared by reacting the ligand precursor with CoCl2·6H2O and can then be recrystallized by allowing diethyl ether to slowly diffuse into an acetonitrile solution that contains the cobalt...
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相关实验视频

Updated: Jan 20, 2026

Catalytic Hydrogenation of Alkene: Applications in Chemistry
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Catalytic Hydrogenation of Alkene: Applications in Chemistry

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在酸上

Murielle F Delley1, Zishan Wu1, M Elizabeth Mundy2

  • 1Department of Chemistry , Yale University , New Haven , Connecticut 06520-8107 , United States.

Journal of the American Chemical Society
|September 4, 2019
PubMed
概括
此摘要是机器生成的。

化物 (CoP) 有效地结合了大量的活性,这对于其在演化反应 (HER) 中作为地球丰富的催化剂的作用至关重要. 这项研究量化了COP表面的体化学和热化学.

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科学领域:

  • 材料科学
  • 催化剂
  • 电化学

背景情况:

  • 化物 (CoP) 是水素演化反应 (HER) 的有希望的地球丰富的催化剂.
  • 了解催化剂表面的结对于优化HER效率至关重要.
  • 对于过渡金属化物,有关结能量的实验数据很少.

研究的目的:

  • 通过实验测量与酸盐 (CoP) 结合的的固体和热化学性质.
  • 在中等尺度和纳米粒子 CoP 上研究的存在和反应性.
  • 根据COP的结特性,对其催化性能提供一个新的视角.

主要方法:

  • 使用化和H原子转移反应量化结合.
  • 通过各种试剂的反应性研究估计结合的自由能量.
  • 使用X射线吸收光谱检测化COP的结构变化.

主要成果:

  • 用H2处理将大量的活性引入COP (大约 每个COP单位的0.2H).
  • 在CoP上估计的H原子的结合自由能量在51-66 kcal mol-1之间.
  • 在化过程中,Operando XAS显示了晶格扩张,并没有显著的变化.

结论:

  • CoP表面含有大量的活性,影响其催化和电催化性能.
  • 实验方法为研究其他材料的结提供了一种方法.
  • 这些发现提供了对HER中的CoP机制和相关反应的基本见解.