基于烯的共价有机框架用于酸蒸气传感
Laura Ascherl1, Emrys W Evans2, Jeffrey Gorman2
1Department of Chemistry and Center for NanoScience (CeNS) , University of Munich (LMU) , Butenandtstraße 5-13 , 81377 Munich , Germany.
Journal of the American Chemical Society
|September 25, 2019
概括
新的共价有机框架 (COF) 使用质子化胺键来检测敏感的酸. 这些以烯为基础的COF表现出颜色变化,使非水性酸溶液的精确分析成为可能.
科学领域:
- 材料科学
- 化学学
- 纳米技术
背景情况:
- 共价有机框架 (COF) 的特性通常由构建块定义.
- 在COF中的化学键被忽视为功能成分.
研究的目的:
- 开发具有功能性 imine 键的新型烯基 COF.
- 调查这些COF的质子化行为和传感能力.
主要方法:
- 基于双孔烯的COF的合成
- 在COF结构中对胺键的质子化研究.
- 用COF薄膜作为酸蒸气传感器的制造和测试.
主要成果:
- 可逆质子化因胺键诱导显著的近红外变化.
- COF薄膜对酸蒸气具有很高的敏感性 (检测极限:35μg L-1).
- 酸色法允许同时确定非水溶液中的度和质子化强度.
结论:
- 胺键可以作为COF的功能组成部分.
- 这些COF作为有效的酸蒸气和非水溶液的色度传感器.
- 这种方法扩大了共价有机框架的多功能性和应用.
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