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Catalysis02:50

Catalysis

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The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Alkenes are converted to 1,2-diols or glycols through a process called dihydroxylation. It involves the addition of two hydroxyl groups across the double bond with two different stereochemical approaches, namely anti and syn. Dihydroxylation using osmium tetroxide progresses with syn stereochemistry.
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用于氧降解催化剂的PdMo二甲

Mingchuan Luo1,2, Zhonglong Zhao3, Yelong Zhang1

  • 1Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing, China.

Nature
|September 27, 2019
PubMed
概括

一种新型的- (PdMo) 双金属催化剂有效地驱动电解质中的氧减和演化反应. 这一突破为可再生能源应用和先进电池提供了稳定,高性能的替代方案.

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科学领域:

  • 材料科学
  • 电化学
  • 可再生能源

背景情况:

  • 电催化过程对于可再生能源至关重要,但缓慢的氧减少 (ORR) 和氧进化 (OER) 动力学是主要的挑战.
  • 类金属催化剂通常需要高活性,但在性介质中价格昂贵且效率较低.

研究的目的:

  • 在性电解质中开发高活性和稳定的ORR和OER电催化剂.
  • 探索-二甲 (PdMo) 作为 Zn-空气和 Li-空气电池的阴极材料的潜力.

主要方法:

  • 合成PdMo双金属,一个亚纳米厚的,高度曲的金属纳米板.
  • 在性电解质中对PdMo双甲的ORR和OER活性和耐久性的电化学表征.
  • 密度函数理论 (DFT) 计算以了解结构-活动关系.

主要成果:

  • PdMo二甲具有高质量活性 (16.37A/mg Pd为ORR) 和超过30,000个周期的稳定性.
  • 获得的质量活性明显高于商业Pt/C和Pd/C催化剂.
  • DFT计算表明由于合金,应变和量子尺寸效应而优化氧结合.

结论:

  • 在性介质中,PdMo二甲是ORR和OER的有希望,高效和稳定的电催化剂.
  • 它的独特结构和电子特性为改进的能量储存和转换设备提供了途径.
  • 金属材料代表了能源电催化剂的新一类有希望的催化剂.