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Updated: Jan 6, 2026

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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通过内分子维尔斯迈耶反应合成和分离抗芳香膨胀阿扎科罗

Kosuke Oki1, Masayoshi Takase1, Shigeki Mori2

  • 1Graduate School of Science and Engineering , Ehime University , Matsuyama 790-8577 , Japan.

Journal of the American Chemical Society
|October 3, 2019
PubMed
概括

研究人员合成了一种扩展的六罗赫萨科罗 (HPHAC) 的反芳香离子. 这种新型化合物表现出24π的反芳香性,通过NMR光谱和计算研究得到证实,并且可以转化为芳香三基.

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