在分支Ni纳米颗粒上直接增长高应力Pt岛屿以改善进化反应活动
Ali Alinezhad1, Lucy Gloag1, Tania M Benedetti1
1School of Chemistry , The University of New South Wales , Sydney , New South Wales 2052 , Australia.
Journal of the American Chemical Society
|October 4, 2019
概括
在 (Ni) 纳米颗粒上生长的高应力 (Pt) 岛增强了演化反应 (HER) 的活性. 调节Pt岛的大小控制了应变,提高了性电解质中的电催化性能.
科学领域:
- 材料科学
- 电化学
- 纳米技术
背景情况:
- 在晶格不匹配的 (Ni) 纳米颗粒上直接生长 (Pt) 岛屿是一个重要的合成障碍.
- 创建高张力Pt原子是先进电催化的一种有前途的方法.
研究的目的:
- 开发一种用于直接在Ni纳米粒子上合成可调节的Pt岛屿的方法.
- 为了研究演化反应 (HER) 的压力Pt岛的电催化活性.
主要方法:
- 使用非常温和的反应条件对分支的Ni纳米粒子进行Pt岛屿的直接生长.
- 标志着Pt岛屿的大小和压力.
- 在pH 13的电解质中评估了HER的性能.
主要成果:
- 在Ni分支粒子上成功形成了Pt岛屿.
- 在分支的Ni纳米颗粒上,高强度的1. 9纳米Pt岛显示出高特异性活性.
- 使用这些纳米结构在pH 13的电解质中达到HER的最高质量活性.
结论:
- 在温和的条件下,可以在Ni纳米颗粒上直接合成应变的Pt岛屿.
- 通过合成控制Pt岛的尺寸,可以进行应变调整,从而提高HER活性.
- 这些发现为优化基于Pt的电催化剂提供了有效的生产途径.
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