通过多核和二维固态核磁共振揭示了以为基础的高效矿太阳能电池的原子级微观结构
Anwar Q Alanazi1, Dominik J Kubicki1,2, Daniel Prochowicz1,3
1Laboratory of Photonics and Interfaces, Institute of Chemical Sciences and Engineering, School of Basic Sciences , Ecole Polytechnique Fédérale de Lausanne , CH-1015 Lausanne , Switzerland.
Journal of the American Chemical Society
|October 9, 2019
概括
用5乙酸 (AVAI) 进行化学注可以稳定矿太阳能电池 (PSC). 这种AVAI处理将设备的效率提高到18.94%并改善长期使用的操作稳定性.
科学领域:
- 材料科学
- 可再生能源
- 固态化学
背景情况:
- 提高矿太阳能电池 (PSC) 的性能和稳定性至关重要.
- α-FAPbI3是一种有前途的矿材料,但其结构稳定性是一个挑战.
研究的目的:
- 调查使用5-氨酸化物 (AVAI) 作为稳定α-FAPbI3矿结构的化学剂.
- 为了阐明AVAI与矿网之间的原子级相互作用.
- 提高公共服务中心的业绩和运营稳定性.
主要方法:
- 固态神奇角旋转核磁共振 (MAS NMR) 光谱用于研究原子级相互作用.
- 密度函数理论 (DFT) 计算以建模稳定结构.
- 暂时吸收光谱 (TAS) 探测电荷载体动态.
- 矿太阳能电池的制造和特征.
主要成果:
- AVAI有效地稳定了α-FAPbI3结构,导致具有大粒度的高度晶体膜.
- 在AVAI修改的薄膜中观察到增长的电荷载体寿命.
- 优化的设备实现了18.94%的最大功率转换效率 (PCE).
- 太阳能电池在连续照明300小时后保持了90%的初始效率.
结论:
- AVAI是一种有效的分子调节器,可以稳定矿结构并提高PSC的性能.
- 这项研究提供了关于原子级稳定机制的见解.
- 基于AVAI的PSC表现出高效率和卓越的运行稳定性,为实际应用铺平了道路.
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