高合金中的调元件分布,结构和特性
Qingqing Ding1, Yin Zhang2, Xiao Chen3
1Center of Electron Microscopy and State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Zhejiang University, Hangzhou, China.
Nature
|October 11, 2019
概括
具有受控元素聚合的新型高合金具有增强的机械性能. 原子尺度映射显示了CrFeCoNiPd合金中的组成波动如何提高强度和可塑性.
科学领域:
- 材料科学
- 金属工程
- 纳米技术
背景情况:
- 由于其复杂的组成,高合金具有独特的机械性能.
- 了解组合-结构-属性关系对于HEA设计至关重要.
- 原子尺度的元素分布显著影响材料的行为.
研究的目的:
- 研究面中心立方体 (FCC) 高合金中的原子尺度元素分布.
- 将Cantor合金 (CrMnFeCoNi) 与新的FCC合金 (CrFeCoNiPd) 进行比较.
- 将元素分布与机械性能和变形机制相关联.
主要方法:
- 分析元素分布的原子分辨率化学映射.
- 在压力实验中进行现场传输电子显微镜 (TEM).
- 脱位滑动,横滑动和相互作用的分析.
主要成果:
- 与均的Cantor合金相比,CrFeCoNiPd合金具有显著的元素聚合 (1-3纳米波长).
- 在CrFeCoNiPd中,纳米级的应变场阻碍了脱位滑动.
- CrFeCoNiPd表现出巨大的脱位交叉滑动和强大的脱位相互作用.
- CrFeCoNiPd表现出更高的强度,同时保持了应变硬化和柔性.
结论:
- 在CrFeCoNiPd中,明显的组成波动和增加的堆叠故障能量驱动独特的变形机制.
- 原子尺度元素映射为设计具有卓越机械性能的HEAs提供了洞察力.
- 定制组合和原子配置是实现卓越材料性能的关键.
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