通过三重融合向上转换通过红光进行光色反应
Ayako Tokunaga1, Lucas Martinez Uriarte2, Katsuya Mutoh1
1Department of Chemistry, School of Science and Engineering , Aoyama Gakuin University , 5-10-1 Fuchinobe , Chuo-ku, Sagamihara , Kanagawa 252-5258 , Japan.
Journal of the American Chemical Society
|October 15, 2019
概括
研究人员开发了一种新的红光驱动的光色系统, 这种高效的单点能量传输策略避免了对先进材料和生物应用有害的紫外线.
科学领域:
- 摄影化学
- 材料科学
- 有机化学
背景情况:
- 对于避免紫外线的应用,红/近红外 (NIR) 光响应分子是可取的.
- 目前用于红色/NIR光色的策略是有限的.
- 三重聚变提供了一种用于化学反应的低能光转换为高能光的方法.
研究的目的:
- 通过三重聚变来证明红光驱动的光色学.
- 开发一种新型的光色系统,对可见光/NIR光具有增强的光敏度.
- 在光色分子中探索高效的能量传递机制.
主要方法:
- 使用一种具有共价键的烯基单元的基- imidazolyl基复合物 (Pery-RPIC).
- 使用秒时间分辨率的吸收和光光谱.
- 从烯消灭器单元到光色单元的单片能量转移.
主要成果:
- 通过三重聚变成功证明红光驱动的光色.
- 从烯单元获得高效的单体能量传输.
- 佩里-RPIC系统显示低能红光的有效转化为光色反应.
结论:
- 开发了可见光和NIR光响应光色系统的新策略.
- 具有高效单元能量转移的三重聚变方法是有效的.
- 这种方法具有超越光色的各种光化学反应的潜力.
相关概念视频
Photochemical Electrocyclic Reactions: Stereochemistry
2.2K
The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Selection Rules: Photochemical Activation
2.2K
Photoreceptors and Visual Pathways
8.6K
At the molecular level, visual signals trigger transformations in photopigment molecules, resulting in changes in the photoreceptor cell's membrane potential. The photon's energy level is denoted by its wavelength, with each specific wavelength of visible light associated with a distinct color. The spectral range of visible light, classified as electromagnetic radiation, spans from 380 to 720 nm. Electromagnetic radiation wavelengths exceeding 720 nm fall under the infrared category,...
8.6K
The Photochemical Reaction Center
5.1K
Reaction centers are pigment-protein complexes that initiate energy conversion from photons to chemical entities. Therefore, photochemical reaction center is a more appropriate term that describes these complexes. The Nobel laureates Robert Emerson and William Arnold provided the first experimental evidence of photochemical reaction centers by demonstrating the participation of nearly 2,500 chlorophyll molecules for the release of just one molecule of oxygen. Despite thousands of photosynthetic...
5.1K
Cycloaddition Reactions: MO Requirements for Photochemical Activation
2.5K
Some cycloaddition reactions are activated by heat, while others are initiated by light. For example, a [2 + 2] cycloaddition between two ethylene molecules occurs only in the presence of light. It is photochemically allowed but thermally forbidden.
2.5K
Photoluminescence: Fluorescence and Phosphorescence
3.4K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
3.4K
Photosystem II
78.2K
The multi-protein complex photosystem II (PS II) harvests photons and transfers their energy through its bound pigments to its reaction center, and ultimately to photosystem I (PSI) through the electron transport chain. The pigments responsible for caputirng the light energy in photosystems include chlorophyll a, chlorophyll b, and carotenoids.
The pigment molecules are arranged across two photosystem domains — the antenna complex and the reaction center. The main aim of the pigment...
The pigment molecules are arranged across two photosystem domains — the antenna complex and the reaction center. The main aim of the pigment...
78.2K


