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Updated: Jan 5, 2026

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使用分子旋转器测量的n→π*相互作用的过渡状态稳定

Erik C Vik1, Ping Li1, Perry J Pellechia1

  • 1Department of Chemistry and Biochemistry , University of South Carolina , Columbia , South Carolina 29208 , United States.

Journal of the American Chemical Society
|October 15, 2019
PubMed
概括

分子旋转器表明,n→π*相互作用显著稳定了键旋转的过渡状态 (TS). 这种稳定性高达10 kcal/mol,通过计算研究和NBO分析得到证实.

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