超电导体的新家族
Laidong Zhou1, Abdeljalil Assoud1, Qiang Zhang2
1Department of Chemistry and the Waterloo Institute for Nanotechnology , University of Waterloo , 200 University Avenue West , Waterloo , Ontario N2L 3G1 , Canada.
Journal of the American Chemical Society
|October 24, 2019
概括
我们发现了具有高离子导电性的新型抗氧化固体电解质. 这些材料显示出先进的固态电池的前景,即使在低温下.
科学领域:
- 材料科学
- 固态化学
- 电化学
背景情况:
- 开发固体电解质对于更安全,更高效的电池至关重要.
- 石是一种有前途的固体离子导体.
- 在此之前,还没有对以为基础的 argyrodites 进行过超离子导电性的研究.
研究的目的:
- 合成和描述一种新型的电导体.
- 研究结构障碍与离子导电性之间的关系.
- 评估这些材料对全固态电池的潜力.
主要方法:
- 固体溶液的合成 Li6+xMxSb1-xS5I (M=Si,Ge,Sn) 这两种类型的固体溶液的合成方法是:
- 使用单晶X射线衍射和同步子/中子粉衍射进行结构分析.
- 通过阻抗光谱进行电化学表征.
主要成果:
- 在新的抗氧化家族中实现了高离子导电性 (高达24mS·cm-1).
- 通过最佳替代诱导的阴离位障碍增强了Li+扩散.
- 观察到低激活能量 (0.25 eV) 和在-78 °C保持导电性.
- 显示与金属阳极的良好兼容性.
结论:
- 新的抗氧化是非常有前途的固体电解质.
- 结构障碍是实现高离子导电性的关键因素.
- 这些材料为开发高性能全固态电池提供了可行的途径.
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