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相关概念视频

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

3.8K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

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Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
13.8K
Catalysis02:50

Catalysis

30.0K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation02:24

Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Introduction
Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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使用单位Pt1/CeO2催化剂从甲醇有效生产

Lu-Ning Chen1, Kai-Peng Hou2, Yi-Sheng Liu

  • 1State Key Laboratory of Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, and Department of Chemistry, College of Chemistry and Chemical Engineering , Xiamen University , Xiamen 361005 , China.

Journal of the American Chemical Society
|October 25, 2019
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概括

单位氧化物催化剂显著提高了从甲醇产生的速度. 这一突破为可持续储能纳米粒子催化剂提供了40-800倍的效率提升.

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科学领域:

  • 催化剂
  • 材料科学
  • 可持续能源

背景情况:

  • 是一种有前途的能源载体,但由于体积能量密度低,它面临储存和运输的挑战.
  • 液态有机载体 (LOHC) 是一个可行的解决方案,因为它们可以在现场产生.
  • 开发高效的催化剂对于具有成本效益和高速度的储和释放至关重要.

研究的目的:

  • 研究从甲醇产生的单位催化剂的有效性.
  • 将单位Pt1/CeO2与传统纳米粒子催化剂的性能进行比较.
  • 探索用于高效可持续能源储存的先进催化材料.

主要方法:

  • 使用甲醇作为液态有机载体.
  • 使用单点Pt1/CeO2催化剂进行现场生成.
  • 与2.5nm和7.0nm Pt/CeO2纳米粒子催化剂的催化性能进行比较.

主要成果:

  • 单位Pt1/CeO2催化剂显示出显著更高的生成效率.
  • 效率是2.5纳米Pt/CeO2样本的40倍.
  • 效率是7.0纳米Pt/CeO2样本的800倍.

结论:

  • 与纳米粒子催化剂相比,单位催化剂在生成方面具有更高的性能.
  • 这项研究证实了单站式催化剂在有效和可持续储能方面的潜力.
  • 这些发现为设计下一代应用的催化剂提供了基础.