高导电和稳定离子交换膜燃料电池中的共价组合的离子高速公路
Yoonseob Kim1,2, Yanming Wang3, Arthur France-Lanord3
1Department of Chemistry , Massachusetts Institute of Technology , Cambridge , Massachusetts 02139 , United States.
Journal of the American Chemical Society
|November 5, 2019
概括
具有"离子高速公路"的新离子交换膜在性燃料电池中提供了增强的导电性和稳定性. 这种设计改善了氧化的运输, 对于高效和持久的能源转换至关重要.
科学领域:
- 材料科学
- 电化学
- 聚合物化学
背景情况:
- 为燃料电池开发稳定,高导电的离子交换膜 (AEM) 是至关重要的.
- 现有的AEM在性环境中难以保持化学和机械稳定性.
- 高效的氧化物运输对于燃料电池的高性能至关重要.
研究的目的:
- 设计和合成具有增强离子导电性和性稳定的新型聚合物膜.
- 研究"离子高速公路"在促进离子运输中的作用.
- 评估这些膜在性燃料电池中的性能.
主要方法:
- 具有电荷移位的酸和同三的交联聚合物膜的合成.
- 包括导电性,吸水性和离子交换能力在内的膜特性.
- 使用金属催化剂进行性稳定性测试和燃料电池性能评估.
主要成果:
- 在80°C时达到111.6 mS cm-1的导电性,吸水率低 (7.9%) 和离子交换能力低 (0.91 mmol g-1).
- 与现有材料相比,在降低的水合和离子交换能力下显示出显著更高的导电性.
- 在30天的性稳定性测试后保持超过75%的初始导电性.
- 一个单一的燃料电池实现了0.73 W cm-2的峰值功率密度和400小时的稳定运行.
结论:
- "离子高速公路"的设计有效地提高了氧化物运输和膜稳定性.
- 这些新膜为高性能性燃料电池提供了有希望的替代品.
- 这些发现为更耐用,更高效的电化学能量转换装置铺平了道路.
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