铜催化,N-定向的Csp3-H三甲基化 (-SCF3-sub) 和三甲基化 (-SeCF3-sub)

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Updated: Jan 4, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes

Published on: July 28, 2018

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Atanu Modak1, Emily N Pinter1, Silas P Cook1

  • 1Department of Chemistry , Indiana University , 800 East Kirkwood Avenue , Bloomington , Indiana 47405 , United States.

Journal of the American Chemical Society
|November 8, 2019
PubMed
概括

一种新的铜催化方法直接与三甲基和三甲基组功能化C-H键. 这种多功能反应与各种功能组兼容,使得复杂的分子可以获得.

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Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
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