印中表面的合成,表征和电化学应用
Sunpet Assavapanumat1,2, Marisa Ketkaew1,2, Alexander Kuhn2
1School of Molecular Science and Engineering, School of Energy Science and Engineering and Nanocatalysts and Nanomaterials for Sustainable Energy and Environment Research Network of NANOTEC , Vidyasirimedhi Institute of Science and Technology , Rayong , 21210 , Thailand.
Journal of the American Chemical Society
|November 8, 2019
概括
研究人员开发了中孔性印尼膜,用于酶选择性合成. 这种成本效益较高的替代可以进行电化学分辨和立体特异性降低具有高反选择性的奇拉化合物.
科学领域:
- 材料科学
- 电化学
- 有机化学
背景情况:
- 在制药和化品中,
- 基于的材料是有效的,但对于手术应用来说很昂贵.
- 开发可负担的合合成替代品是关键的研究目标.
研究的目的:
- 作为的成本效益高的替代品,研究半孔性印.
- 评估基于的印材料的电化学特性.
- 使用这些薄膜来证明前体化合物的立体特异性电减.
主要方法:
- 在模板和液晶相的存在下,的电沉积.
- 半孔印尼膜的制造
- 电化学表征和反选择性评估.
主要成果:
- 成功制造了半孔印尼膜.
- 已经证明了电化学差异化.
- 一种具有高达80%的反选择性 (ee) 的前体性化合物的立体特异性电降解.
结论:
- 半孔印尼为提供了一个有希望的,低成本的替代品.
- 这些基于的材料可以作为电催化剂用于不对称的合成.
- 这些发现为开发可负担的非贵金属矩阵提供了机会.
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