一个高度发光的状四面体 Eu4L4(L') 4 :性诱导,性记忆和循环极化发光
Yanyan Zhou1, Hongfeng Li1, Tianyu Zhu1
1Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials Science , Heilongjiang University , Harbin 150080 , People's Republic of China.
Journal of the American Chemical Society
|November 21, 2019
概括
研究人员开发了一种新方法,用循环极化发光 (CPL) 来制造纯净的兰坦化物. 这一突破使得有效的反选择性传感成为可能,并证明了在兰坦化物组合中具有新奇的性记忆效应.
科学领域:
- 协调化学
- 超分子化学
- 发光和光子学
背景情况:
- 具有循环极化发光 (CPL) 的状兰坦化物对于反选择性识别和传感至关重要.
- 由于兰酸离子的可变性,开发用于 homochiral lanthanide 的选择性组装的强有力的方法具有挑战性.
研究的目的:
- 报告第一个enantiopure lanthanide四面体的形成使用合辅助连接体诱导策略.
- 研究这些新奇的体的CPL特性和发光量子产量.
- 探索以兰他尼德为基础的组件中性记忆效应的潜力.
主要方法:
- 使用阿基拉三-二基 (L) 和基拉R/S-bis (R/S-BINAPO) 辅助连接物组装一个Eu(III) 四面体.
- 使用X射线结晶学,NMR和CD光谱学的结构特征.
- 光物理特性包括CPL测量和发光量子产量确定.
主要成果:
- 化四面体的形成, (Eu4L4) ((R/S-BINAPO) 4 (ΔΔΔ-1 和 ΛΛΛ-1).
- 观察到强大的CPL (达0.20) 和超高的发光量子产量 (QYs高达81%).
- 证明一种性记忆效应:在与性DPEPO进行配体交换后,性保持,产生具有显著CPL和QY的新反素 (ΔΔΔΔ-2和ΛΛΛ-2).
结论:
- 已经建立了一个简单而强大的合成具有CPL特性的enantiopure lanthanide的策略.
- 开发的子显示出出色的发光效率和CPL,在奇拉传感中具有潜在的应用.
- 在兰化物组合中发现了性记忆效应,为设计性材料开辟了新的途径.
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