来自单个Mn-doped矿微晶的激发依赖的发射色调
Qi Sun1,2, Shiping Wang1,2, Chunyi Zhao1,2
1State Key Laboratory of Molecular Reaction Dynamics and the Dynamic Research Center for Energy and Environmental Materials , Dalian Institute of Chemical Physics, Chinese Academy of Sciences , Dalian 116023 , China.
Journal of the American Chemical Society
|December 4, 2019
概括
这项研究报告了添加的矿微晶体, 通过调整激光激发可以将发射颜色从色转变为蓝色. 这种依赖激发的色调是可逆和稳定的,为新的纳米光子设备铺平了道路.
科学领域:
- 材料科学
- 纳米技术
- 光电子产品
背景情况:
- 双价 (Mn2+) 化矿材料具有独特的光学,磁性和电性.
- 矿微晶 (MCs) 在先进的光学应用中具有前景.
研究的目的:
- 在单个Mn-doped CsPbCl3微晶体中报告激发依赖的发射色调.
- 研究内部能量转移 (IET) 的机制及其在色调中的作用.
主要方法:
- 光发光 (PL) 光谱
- 过渡光谱学
- 取决于温度的PL测量
- 控制激光激发强度和重复率的变化.
主要成果:
- 在Mn-doped CsPbCl3 MC中实现了从色到蓝色的广泛,可逆和连续的调色.
- 通过IET证明宿主激子 (蓝色) 和Mn-dopants (色) 的双色辐射.
- 识别了浅的陷状态,可以调节激素与剂的IET,在高激发时引起排放和.
结论:
- 化CsPbCl3MC具有稳定,可切换颜色的发射特性.
- 观察到的色调机制归因于通过陷状态的瓶能量传输.
- 这些材料显示了纳米光子设备的应用潜力,需要单颗粒色彩切换.
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