基于纯金属有机框架微晶的绝缘阻碍控制激光开关
Yuanchao Lv1, Zhile Xiong1, Zizhu Yao1
1Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science , Fujian Normal University , Fuzhou 350007 , China.
Journal of the American Chemical Society
|December 7, 2019
概括
研究人员开发了一种使用金属有机框架 (MOF) 微晶的新型激光开关. 这种以立体阻力控制的装置可实现双波长激光的可逆切换,为先进的微型和纳米激光器铺平了道路.
科学领域:
- 材料科学
- 光学和光学
- 超分子化学
背景情况:
- 金属有机框架 (MOF) 是具有可调节性质的晶体多孔材料.
- 聚合诱导辐射 (AIE) 发光剂在光学应用中具有独特的光物理特性.
- 费布里-佩罗微激光器需要特定的光学增益和空腔条件.
研究的目的:
- 在纯的MOF微晶体中演示一个硬质阻力控制的激光开关.
- 为了研究硬体阻碍,链接器旋转和激光行为之间的关系.
- 在基于MOF的微激光器中实现双波长激光的可逆切换.
主要方法:
- 用AIE发光剂作为连接器的多面MOF微电线的制造.
- 使用客分子脱吸/吸附来调节AIE链接器周围的硬质阻碍.
- 描述MOF微激光器的光学增益和激光性能.
- 根据硬质环境观察连接器旋转和发射光谱的变化.
主要成果:
- 带有AIE连接器的MOF微线可以作为Fabry-Pérot微激光器.
- 降低硬体阻碍导致左侧旋转增强和红移增强.
- 通过控制立体阻碍实现了双波长激光的可逆切换.
- 激光开关显示基于客分子相互作用的可调节增益行为.
结论:
- 立体阻抗控制为MOF中的激光特性提供了一种新的机制.
- 开发的基于MOF的激光开关具有多功能和可逆性.
- 这项工作为设计各种应用的先进微型和纳米激光器提供了一个有前途的策略.
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