立方/六角石芯/铜硫化物纳米晶体的合成和光学特性
Jiajia Ning1, Stephen V Kershaw1, Andrey L Rogach1
1Department of Materials Science and Engineering, and Centre for Functional Photonics , City University of Hong Kong , 83 Tat Chee Avenue , Kowloon, Hong Kong SAR , People's Republic of China.
Journal of the American Chemical Society
|December 14, 2019
概括
研究人员开发了无重金属的铜二硫化物 (CuInS2) 纳米晶体,具有独特的核心/外结构. 这些异相纳米晶体具有可调节的近红外光学特性,为先进的应用提供了潜力.
科学领域:
- 材料科学
- 纳米技术
- 固态物理
背景情况:
- 无重金属的半导体纳米晶体对于各种应用是可取的.
- 铜二硫化物 (CuInS2) 是光电子器件的一个有前途的材料.
研究的目的:
- 开发一种无重金属异相核心/外CuInS2纳米晶体的合成方法.
- 研究外厚度对这些纳米晶体的光学特性的影响.
主要方法:
- 核心/外 CuInS2 纳米晶体与立方 (CP) 核心和六角 (WZ) 的合成.
- 使用光谱学的纳米晶体结构和光学特性.
主要成果:
- 成功合成异相CP/WZ核心/外CuInS2纳米晶体.
- 随着外厚度的增加,观察到吸收和光发光谱的红移.
- 证明了II型异构结构与光发光动态的行为.
结论:
- CP和WZ外之间的接口显著影响光发光量子产量.
- 这些异相纳米晶体提供可调节的近红外辐射.
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