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相关概念视频

Chair Conformation of Cyclohexane02:02

Chair Conformation of Cyclohexane

17.7K
The chair conformation is the most stable form of cyclohexane due to the absence of angle and torsional strain. The absence of angle strain is a result of cyclohexane’s bond angle being very close to the ideal tetrahedral bond angle of 109.5° in its chair conformer. Similarly, the torsional strain is also absent owing to the perfectly staggered arrangement of bonds.
The hydrogen atoms linked to carbons are arranged in two different axial and equatorial orientations to achieve this...
17.7K
Conformations of Cyclohexane02:11

Conformations of Cyclohexane

15.0K
Cyclohexane does not exist in a planar form due to the high angle and torsional strain it would experience in the planar structure. Instead, it adopts non-planar chair and boat conformations.
The chair form is the most stable and derives its name from its resemblance to the “easy chair.” In the chair conformation, two carbon atoms are arranged out-of-plane — one above and one below, minimizing the torsional strain. In the chair form, the bond angle is very close to the ideal...
15.0K
Structure of Alkanes02:23

Structure of Alkanes

32.1K
The formation of carbon-carbon bonds leading to the creation of the carbon chain is the basis of organic chemistry. August Kekulé and Archibald Scott Couper independently developed this idea of carbon chain formation.
Hydrocarbons are the simplest organic compounds composed of carbons and hydrogens. Based on the bond order between carbons, the hydrocarbons are further classified into alkanes, alkenes, and alkynes. 
Alkanes are the simplest hydrocarbons with sp3 hybrid carbon atoms....
32.1K
Conformations of Cycloalkanes02:29

Conformations of Cycloalkanes

13.9K
Adolf von Baeyer attempted to explain the instabilities of small and large cycloalkane rings using the concept of angle strain — the strain caused by the deviation of bond angles from the ideal 109.5° tetrahedral value for sp3  hybridized carbons. However, while cyclopropane and cyclobutane are strained, as expected from their highly compressed bond angles, cyclopentane is more strained than predicted, and cyclohexane is virtually strain-free. Hence, Baeyer’s theory that...
13.9K
Conformations of Butane02:20

Conformations of Butane

17.4K
Unlike ethane and propane that have only two major conformations, butane has more than two conformers. The staggered form of butane in which the bulky methyl groups on the two carbons are placed on opposite sides, that is, at a dihedral angle of 180°, is the lowest energy, most stable form — called the anti conformer. This conformation is stabilized due to the absence of steric repulsion between the largely spaced out methyl groups. The other two staggered conformations are...
17.4K
Conformations of Ethane and Propane02:18

Conformations of Ethane and Propane

16.6K
In an organic molecule, free rotation about the carbon-carbon single bond results in energetically different conformers of the molecule. Due to this rotation, called the internal rotation, ethane has two major conformations — staggered and eclipsed.
Staggered conformation is a low energy and more stable conformation with the C-H bonds on the front carbon placed at 60°dihedral angles relative to the C-H bonds on the back carbon, leading to a reduced torsional strain. In staggered...
16.6K

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相关实验视频

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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

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有截断圆结构的碳化合物带

Qian Zhang1, Yan-E Zhang1, Shuo Tong1

  • 1MOE Key Laboratory of Bioorganic Phosphorous Chemistry and Chemical Biology, Department of Chemistry , Tsinghua University , Beijing , 100084 , China.

Journal of the American Chemical Society
|January 7, 2020
PubMed
概括

研究人员使用素原始材料制造出新的碳化合物带. 这些分子带可以选择性地容纳甲和p-xylen等小分子.

科学领域:

  • 超分子化学
  • 有机合成
  • 材料科学

背景情况:

  • 复杂分子架构的多功能平台.
  • 开发具有定制腔的新型宿主材料对于分子识别和分离至关重要.

研究的目的:

  • 合成和描述一种新的碳化合物带,
  • 探索这些新型分子带的结构多样性和宿主-客房属性.

主要方法:

  • 使用关闭所有峡湾的策略,包括微缩,过渡金属催化乙烯和分子内甲基.
  • 使用olefin和子子单位的选择性化产生多种碳化合物结构.
  • 使用光谱和晶体学技术对合成化合物进行了表征.

主要成果:

  • 成功合成带[n]arene[n]tropilidenes (n = 4, 6) 具有双链宏环带结构.
  • 发现分子带的腔体是截断的体.
  • 证明碳化合物带有选择性地包含甲和p-xylen等小分子的能力.

结论:

  • 开发的合成策略可以轻松获得新型碳化合物带.
  • 这些分子带具有独特的结构特征,并作为有效的合成宿主材料发挥作用.

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Kinematic History of a Salient-recess Junction Explored through a Combined Approach of Field Data and Analog Sandbox Modeling
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  • 小分子的选择性包含突出了它们在宿主-客化学和分离科学中的潜在应用.