直接和可扩展的电还原三酸到三酸
Shuhei Manabe1, Curt M Wong1, Christo S Sevov1
1Department of Chemistry and Biochemistry , The Ohio State University , 151 West Woodruff Avenue , Columbus , Ohio 43210 , United States.
Journal of the American Chemical Society
|January 18, 2020
概括
这项研究提出了一种新的电化学方法,有效地将三酸 (TPPO) 转化为三酸 (TPP). 这种可扩展的过程减少了合成有机化学的浪费和成本.
科学领域:
- 有机化学
- 电化学
- 绿色化学
背景情况:
- 三氧化物 (TPPO) 是常见的有机反应的静态度副产物.
- 在大规模合成中,将TPPO回收为三酸 (TPP) 对于降低成本和减少废物至关重要.
- 从TPPO到TPP的直接和可扩展的电力减排是一个未解决的挑战.
研究的目的:
- 开发一个直接的,单步电化学方法来降低TPPO到TPP.
- 通过TPP回收来实现成本效益和可持续的合成.
- 展示开发的电化学方法的稳定性和可扩展性.
主要方法:
- 使用阳极的电化学减少TPPO.
- 使用支持电解质从阳极氧化产物中再生易斯酸.
- 采用温和的电位和条件,有利于P-O键裂变而不是P-C键裂变.
主要成果:
- 从TPPO到TPP的单阶段电减成功实现.
- 该方法选择性地形成TPP,最大限度地减少副产品的形成.
- 该过程应用于各种氧化物,维蒂格反应的副产品和克尺度的减少.
- 在高电流密度下证明了高度 (1M) 的流量减少.
结论:
- 已经建立了一个强大的和可扩展的电化学方法,用于TPPO转换为TPP.
- 这种方法提供了一种可持续的解决方案,以减少在TPP中介反应中的浪费和成本.
- 开发的方法在合成有机化学和工业过程中具有广泛的应用.
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