轴依导极性的化学设计原理
Yaxian Wang1, Karl G Koster2, Andrew M Ochs2
1Department of Materials Science and Engineering , The Ohio State University , Columbus , Ohio 43210 , United States.
Journal of the American Chemical Society
|January 22, 2020
概括
研究人员发现了具有双n型和p型导电性的材料, 本研究概述了设计原则,并确定了这些应用的有前途的分层材料.
科学领域:
- 材料科学
- 固态物理
- 凝聚物质物理学
背景情况:
- 最近的发现显示材料在不同的晶体轴上表现出n型和p型导电.
- 这种双极性行为对电子和能源采集技术具有重大潜力.
研究的目的:
- 建立与轴相依导极性的材料的化学设计原则.
- 确定这种现象的机制和带结构指纹.
- 探索这种材料在分层化合物中的普遍性和设计.
主要方法:
- 使用第一原理预测来研究材料特性.
- 定义传导极性的单载体和多载体机制.
- 使用分子轨道理论来分析带结构 (例如,BaCuAs).
主要成果:
- 已识别的AMX化合物 (A = Ca,Sr,Ba;M = Cu,Ag,Au;X = P,As,Sb) 显示了所需的行为.
- 证明这些分层材料可以显示平面内p型和交叉平面n型导电.
- 显示导电机制取决于剂水平和晶体结构.
结论:
- 通过分层材料的特定化学设计,可以实现轴依赖导电极性.
- 这项研究为识别和设计具有这种独特电子特性的新材料提供了框架.
- 这项研究为新型电子和能源采集设备铺平了道路.
相关概念视频
Charging Conductors By Induction
8.9K
The Earth is a good conductor of electricity, and it is so big that it can be considered an infinite source or sink of charges. It can easily exchange charges with any matter.
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
Generally, conductors like metals do not allow any excess charge to be present on them. Any excess charge added to metals easily flows away, for example, when a metal is placed on the Earth. This process is called earthing.
However, conductors can be charged by a process called induction. For example, consider charging a...
8.9K
Propagation of Action Potentials
8.6K
The propagation of an action potential refers to the process by which a nerve impulse, or "action potential," travels along a neuron.
Neurons (nerve cells) have a resting membrane potential, with a slightly negative charge inside compared to outside. This is maintained by ion channels, such as sodium (Na+) and potassium (K+) channels, which control the flow of ions. When a stimulus, like a touch or a signal from another neuron, triggers the neuron, sodium channels open, allowing sodium ions to...
Neurons (nerve cells) have a resting membrane potential, with a slightly negative charge inside compared to outside. This is maintained by ion channels, such as sodium (Na+) and potassium (K+) channels, which control the flow of ions. When a stimulus, like a touch or a signal from another neuron, triggers the neuron, sodium channels open, allowing sodium ions to...
8.6K
Electric Field Inside a Conductor
7.1K
When a conductor is placed in an external electric field, the free charges in the conductor redistribute and very quickly reach electrostatic equilibrium. The resulting charge distribution and its electric field have many interesting properties, which can be investigated with the help of Gauss's law.
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...
Suppose a piece of metal is placed near a positive charge. The free electrons in the metal are attracted to the external positive charge and migrate freely toward that region. This region then...
7.1K
Induced Electric Dipoles
4.7K
A permanent electric dipole orients itself along an external electric field. This rotation can be quantified by defining the potential energy because the external torque does work in rotating it. Then, the potential energy is minimum at the parallel configuration and maximum at the antiparallel configuration. While the former is a stable equilibrium, the latter is an unstable equilibrium.
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
Since the absolute value of potential energy holds no physical meaning, its zero value can be chosen as per...
4.7K
Boundary Conditions for Current Density
1.3K
Current density becomes discontinuous across an interface of materials with different electrical conductivities. The normal component of the current density is continuous across the boundary.
1.3K
Equipotential Surfaces and Conductors
4.3K
For a conductor in which all charges are at rest, the conductor's surface is equipotential. The electric field is always perpendicular to equipotential surfaces. Therefore, in a conductor with static charges, the electric field just outside the conductor is always perpendicular to the conductor's surface. Any tangential component of the electric field will cause charges to move inside the conductor, which will violate the electrostatic nature of the system. In an electrostatic...
4.3K


