带利和带对齐使高质量因子能够提高n型PbS的热电性能
Yu Xiao1, Dongyang Wang1, Yang Zhang2
1School of Materials Science and Engineering , Beihang University , Beijing 100191 , P. R. China.
Journal of the American Chemical Society
|February 5, 2020
概括
在硫化中加入合金和化可以提高热电性能. 这项研究的最大优点 (ZT) 约为1.3,优于其他硫化材料.
科学领域:
- 材料科学
- 固态物理
- 能源转换
背景情况:
- 基于硫化 (PbS) 的热电提供了低成本的,大量存在于地球上的化 (PbTe) 替代品.
- 在n型PbS中优化热电功率 (ZT) 对于高效的能量转换至关重要.
研究的目的:
- 通过协同优化增强n型PbS的热电性能.
- 研究 (Sn) 合金和 telluride (PbTe) 阶段在 PbS 的 ZT 的影响.
主要方法:
- 在PbS矩阵中引入了Sn合金.
- 在合金PbS中加入PbTe阶段.
- 包括功率因子和热导率在内的热电特性被系统地评估.
主要成果:
- 在n型PbS中,最大ZT在923K达到1. 3左右.
- 合金提高了导电带,提高了载体的移动性,并实现了约19.8μWcm-2K-2的峰值功率系数.
- 将8%的PbTe纳入Pb0.94Sn0.06S抑制了晶格导热率到~0.61 Wm-1K-1,导致平均ZT为~0.72从300-923 K.
结论:
- 合金和PbTe的协同优化显著提高了n型PbS的热电性能.
- 开发的Pb0.94Sn0.06S-8%PbTe材料与其他n型PbS基材料相比,具有优越的热电性能.
- 这项工作为开发高效且具有成本效益的基于PbS的热电材料提出了有希望的战略.
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