液体有机框架:单一网络"水管工的梦"双连续立方体液晶
Silvio Poppe1, Xiaohong Cheng1,2, Changlong Chen3
1Institute of Chemistry , Martin-Luther-University Halle-Wittenberg , Kurt-Mothes-Straße 2 , 06120 Halle , Germany.
Journal of the American Chemical Society
|February 6, 2020
概括
研究人员开发了新型的波拉多, 创造了最简单的软物质立方相. 这种独特的液晶结构由状的芳香棒和结组成.
科学领域:
- 材料科学
- 超分子化学
- 流体晶体
背景情况:
- 软物质阶段表现出复杂的自我组装.
- 设计有序的纳米结构对于先进的材料至关重要.
研究的目的:
- 为了合成和描述新型的波拉多.
- 调查新的软物质立方相的形成.
主要方法:
- 具有特定芳香核和功能组的玻拉多的合成.
- 使用像X射线衍射这样的技术来确定相位的结构分析.
主要成果:
- 形成第一个"单一水管工的梦网络",一个立方液晶相 (Pm3̅m).
- 该结构由芳香棒束组成,形成状的网格与结.
- 侧链有效地填充了这个不透的框架中的剩余体积.
结论:
- Bolapolyphiles可以自组成已知的最简单的软物质立方相.
- 这一发现为潜在的应用提供了一个新的,高度有序的有机框架.
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