基燃料电池氧降低电催化剂的组合研究
Yao Yang1, Guanyu Chen2, Rui Zeng1
1Department of Chemistry and Chemical Biology , Cornell University , Ithaca , New York 14853 , United States.
Journal of the American Chemical Society
|February 7, 2020
概括
研究人员开发了燃料电池催化剂的快速选方法. -铜 (Pd-Cu) 合金显示出高氧降解反应 (ORR) 的活性,为高效电动汽车铺平了道路.
科学领域:
- 材料科学
- 电化学
- 可再生能源
背景情况:
- 燃料电池是电动汽车的关键,但需要高效的催化剂来减少氧反应 (ORR).
- 目前的基催化剂价格昂贵,需要开发低成本,高活性的替代品.
研究的目的:
- 开发一种高通量选方法,用于确定ORR的有前途的非电催化剂.
- 评估用于燃料电池应用的铜 (Pd-Cu) 二元合金的催化性能.
主要方法:
- 使用磁喷射的Pd-Cu薄膜电极的组合合成.
- 使用可更换玻璃碳盘电极 (RDE) 测量ORR活动的快速评估.
- 基于碳的PdCu纳米粒子的合成和表征.
主要成果:
- 在九种Pd-Cu化合物中,Pd50Cu50合金表现出最高的ORR活性.
- 与Pd/C相比,PdCu纳米粒子具有3倍的质量特异性和2.5倍的表面特异性活性.
- 在长时间循环后,PdCu/C显示出极好的耐用性.
结论:
- 组合方法可以有效地选燃料电池电催化剂的二元和三元合金.
- 在ORR催化过程中,PdCu合金是金的有前途,具有成本效益的替代品.
- 这种方法可以加速为清洁能源技术开发先进的电催化剂.
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