相关实验视频
Updated: Dec 28, 2025

07:04
Synthesis of Strong Adhesive Hydrogel, Gelatin O-Nitrosobenzaldehyde
Published on: November 11, 2022
2.9K
仿生粘合剂中的弱键增强性和性能
Michael G Mazzotta1, Amelia A Putnam1, Michael A North1
1Department of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907-2084, United States.
Journal of the American Chemical Society
|February 19, 2020
概括
研究人员开发了一种仿生粘合剂, 这种方法模仿自然材料, 创造强而柔软的合成粘合剂用于先进应用.
科学领域:
- 材料科学
- 聚合物化学
- 生物模拟学
背景情况:
- 设计高性能粘合剂需要平衡强度和柔性,这两者往往是矛盾的特性.
- 生物材料通过等级结构和弱键实现性,为合成材料提供了模型.
研究的目的:
- 研究一种生物模拟方法来制造具有增强性和可塑性的合成粘合剂.
- 探索合成聚合物中牺牲键的使用以消除机械应力.
主要方法:
- 合成了一种仿生粘合聚合物,
- 纳入双功能添加剂,如乙烯糖醇,形成一个聚合物网络.
- 使用光谱和物理方法分析材料属性和粘合.
主要成果:
- 双功能添加剂降低了系统模量,同时显著提高了粘合性能.
- 形成了一个弱键的聚合物网络,增强了材料的性.
- 牺牲键有效地消散了机械应力,保护了粘合基质.
结论:
- 使用牺牲键的仿生策略可以在合成粘合剂中实现强度和延展性的平衡.
- 这种方法为设计用于电子,运输和航空航天的高性能材料提供了一般原则.
- 模仿生物策略为克服固有的物质性质矛盾提供了途径.
相关概念视频
Bonding and Strength of Aggregate
393
The bond between aggregate particles and the cement matrix is significantly influenced by the shape and surface texture of the aggregates. High-strength concretes benefit from a rougher texture, which leads to stronger bonding due to greater adhesion. Angular aggregates with larger surface areas also enhance this bond. The bonding quality, however, is complex to assess as no universally accepted test exists. Good bonding is indicated when a crushed concrete specimen shows some aggregate...
393
Cell-matrix's Response to Mechanical Forces
3.3K
In animal cells, the extracellular matrix allows cells within tissues to withstand external stresses and transmits signals from the outside of the cell to the inside. The extracellular matrix is extensive, and its composition varies between different types of tissues. For example, the reticular fibers and ground substance make up the ECM in loose connective tissue, while collagen and bone minerals make up the ECM of bone tissue.
Anchoring junctions mechanically attach a cell to the...
Anchoring junctions mechanically attach a cell to the...
3.3K
Noncovalent Attractions in Biomolecules
62.9K
Noncovalent attractions are associations within and between molecules that influence the shape and structural stability of complexes. These interactions differ from covalent bonding in that they do not involve sharing of electrons.
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
Four types of noncovalent interactions are hydrogen bonds, van der Waals forces, ionic bonds, and hydrophobic interactions.
Hydrogen bonding results from the electrostatic attraction of a hydrogen atom covalently bonded to a strong-electronegative atom like oxygen,...
62.9K
Adhesion
43.2K
Adhesion occurs when one type of molecule is attracted to a different molecule. Water exhibits adhesive properties in the presence of polar surfaces, such as glass or cellulose in plants. For instance, when water is poured into a glass, the positively charged hydrogen molecules of water are more attracted to the negatively charged oxygen molecules in the silica than to the oxygen in neighboring water molecules.
Capillary action is a result of water’s adhesive tendencies. When a narrow...
Capillary action is a result of water’s adhesive tendencies. When a narrow...
43.2K
Cohesion
58.0K
Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a...
On a...
58.0K
Tension Response at Adherens Junctions
3.4K
The adherens junctions that anchor cells together are multi-protein complexes that dynamically adapt to mechanical stimuli such as tensile forces and shear stress. Mechanosensory proteins in these junctions can sense such mechanical stimuli and undergo a shift in their conformation, resulting in an altered function — a process called mechanotransduction.
α-Catenin as a Mechanosensory Protein
The α-catenin of adherens junctions is an allosteric protein with three VH (vinculin...
α-Catenin as a Mechanosensory Protein
The α-catenin of adherens junctions is an allosteric protein with three VH (vinculin...
3.4K

