超高密度的气体分子被限制在环境水中的表面纳米泡中
Limin Zhou1,2,3,4, Xingya Wang1,2,3, Hyun-Joon Shin4
1Shanghai Synchrotron Radiation Facility, Shanghai Advanced Research Institute, Chinese Academy of Sciences, Shanghai 201204, People's Republic of China.
Journal of the American Chemical Society
|March 1, 2020
概括
表面的纳米泡捕获了高度缩的氧气,解释了它们令人惊的稳定性. 这种情况发生在超和液体中,因为气体保持密度不理想.
科学领域:
- 物理化学
- 材料科学
- 纳米技术
背景情况:
- 纳米气泡的长期稳定性仍然不太清楚.
- 探测表面纳米泡的内在特性对于解释它们令人费解的持久性至关重要.
研究的目的:
- 研究纳米气泡的性质和特性.
- 阐明导致表面纳米泡意外稳定的因素.
主要方法:
- 使用基于同步射线的扫描传输X射线显微镜 (STXM) 来分析氧气纳米泡.
- 用分子动力学模拟来模拟超和溶液中的纳米泡行为.
主要成果:
- 在表面的纳米气泡中,STXM发现了高度凝聚的氧气,其密度比大气压力高1-2个数量级.
- 在高氧和液体中观察到纳米气泡,其度远远超过平衡溶解度.
- 模拟证实,封闭的气体分子在超和液体中保持密度.
结论:
- 纳米泡中的高密度气体,由超和的液体环境维持,解释了它们的长期稳定性.
- 这些发现为纳米气体聚合和封闭气体的行为提供了洞察力.
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