显示高Na型P2层氧化物作为先进的离子阴极
Chenglong Zhao1,2, Zhenpeng Yao3, Qidi Wang4,5
1Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China.
Journal of the American Chemical Society
|March 3, 2020
概括
P2型层氧化物的高含量提高了离子电池的结构稳定性和电化学性能. 这一发现为先进的阴极材料提供了提高的离子流动性和延长的循环寿命.
科学领域:
- 材料科学
- 电化学
- 无机化学
背景情况:
- 由于它们的调节性特性,分层氧化物 (NaTMO2) 对离子电池至关重要.
- 组成的多样性影响结构化学,离子导电性和氧化还原活性.
研究的目的:
- 研究P2类层氧化物最大含量的影响.
- 了解高含量如何影响结构稳定性和电化学性能.
主要方法:
- 探测具有不同Na含量的P2类层氧化物组成.
- 对结构稳定性,离子导电性和氧化还原行为的分析.
- 电化学测试以评估储存能力和循环寿命.
主要成果:
- 高含量增强结构稳定性,并促进氧化 (Ni2+到更高的状态).
- 增加的O2p-TM3d-e混合改进了Na-ion的移动性和存储能力 (>100 mAh-1).
- 通过防止有害的P2-O2结构转变,材料具有超长的循环寿命 (3000个循环).
结论:
- 高含量P2型材料为离子电池阴极提供了卓越的电化学性能.
- 这些发现为先进的阴极材料的电子和结构化学提供了新的见解.
- 这项研究扩大了高含量的P2类层氧化物在储能应用中的潜力.
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