在NiO矩阵上超高负载单个原子以显著增强氧气演化反应
Qi Wang1, Xiang Huang, Zhi Liang Zhao
1Department of Materials Science & Engineering, University of Science and Technology of China, Hefei 230026, People's Republic of China.
Journal of the American Chemical Society
|March 17, 2020
概括
研究人员开发了一种高负载的氧化物单原子电催化剂,用于氧化演化反应 (OER). 这种先进的催化剂显著提高了性电解质的能量转化效率.
科学领域:
- 材料科学
- 电化学
- 催化剂
背景情况:
- 单原子电催化剂的能量转化效率很高,但实现高负载仍然是一个挑战.
- 氧化演化反应 (OER) 对于储能和转化应用至关重要.
研究的目的:
- 开发一种简单且经济的高负载单原子电催化剂的合成方法.
- 在氧化物演化反应上研究单个原子的电催化性能.
主要方法:
- 在高负荷的氧化矩阵上合成单个原子 (∼18 wt%).
- 在性电解质中氧化演化反应 (OER) 的催化剂的电化学特征.
- 先进的特征技术包括X射线吸收光谱和偏差校正的Z对比成像.
- 密度函数理论 (DFT) 计算以了解催化机制.
主要成果:
- 在NiO上实现了前所未有的高负荷单个Ir原子 (∼18%).
- 在10 mA cm-2时显示出215 mV的超电位的优异OER性能.
- 与NiO和IrO2相比,OER电流密度显著提高.
- 通过Ir-O结合和有利的Ir氧化状态 (∼4+) 稳定了NiO表面上的Ir原子分散.
- DFT计算显示了单个Ir原子和NiO之间的协同效应,增强了表面反应性.
结论:
- 开发的方法可用于其他系统的高负载单原子催化剂合成.
- 由于协同效应,高负载单原子催化剂表现出极好的OER性能.
- 这项工作为单原子催化剂在能源转化中的工业应用铺平了道路.
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