在共价有机框架之间切换动态网络的实时分子规模成像
Gaolei Zhan1, Zhen-Feng Cai1, Marta Martínez-Abadía2
1Department of Chemistry, Division of Molecular Imaging and Photonics, KU Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium.
Journal of the American Chemical Society
|March 21, 2020
概括
一个电场触发了与素结合的共价有机框架 (COF) 在室温下转化为与酸结合的COF. 这项研究揭示了动态共价库 (DCL) 和网络切换过程中的适应性行为.
科学领域:
- 材料科学
- 化学学
- 纳米技术
背景情况:
- 共价有机框架 (COF) 是具有可调节性质的晶体多孔聚合物.
- 动态共价化学 (DCC) 能够形成适应性材料.
- 在表面合成提供精确的材料组装控制.
研究的目的:
- 研究氧化与酸结合的COF在现场表面的转化.
- 探索电场在室温下催化这种转变中的作用.
- 了解生成的动态共价库 (DCL) 中的自适应行为和动态网络切换.
主要方法:
- 使用扫描道显微镜 (STM) 在现场监测表面转换过程.
- 使用电场刺激触发和催化转化.
- 创建和分析动态共价库 (DCL) 来研究适应性行为.
主要成果:
- 在室温下,成功地证明了电场触发的氧结合COF转化为酸结合COF.
- 在转换过程中观察并描述动态共价库 (DCL) 的适应性行为.
- 提供了COF动态网络切换机制的详细见解.
结论:
- 电场催化在环境温度下提供了新的表面COF转化途径.
- 这项研究阐明了COF中的动态共价网络重组的基本原则.
- 这项工作为设计基于COF的响应性和适应性材料铺平了道路.
相关概念视频
Molecular Models
Physical models representing molecular architectures of chemical compounds play essential roles in understanding chemistry. The use of molecular models makes it easier to visualize the structures and shapes of atoms and molecules.
Network Covalent Solids
Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
Transformers in Distribution System
Transformers in distribution systems can be broadly categorized into distribution substation transformers and other distribution transformers. They are crucial for stepping down high transmission voltages to levels suitable for distribution and end-user applications.
Distribution substation transformers come in various ratings and typically use mineral oil for insulation and cooling. To prevent moisture and air from entering the oil, some transformers use an inert gas like nitrogen to fill the...
Distribution substation transformers come in various ratings and typically use mineral oil for insulation and cooling. To prevent moisture and air from entering the oil, some transformers use an inert gas like nitrogen to fill the...
Sequence Networks of Rotating Machines
A Y-connected synchronous generator, grounded through a neutral impedance, is designed to produce balanced internal phase voltages with only positive-sequence components. The generator's sequence networks include a source voltage that is exclusively in the positive-sequence network. The sequence components of line-to-ground voltages at the generator terminals illustrate this configuration.
Zero-sequence current induces a voltage drop across the generator's neutral impedance and other...
Zero-sequence current induces a voltage drop across the generator's neutral impedance and other...
Two-Compartment Open Model: Overview
Multicompartmental models are crucial tools in pharmacokinetics, providing a framework to understand how drugs move within the body. The two-compartment model is a crucial subtype, segmenting the body into central and peripheral compartments. The central compartment represents areas with high blood flow, such as plasma and highly perfused organs like the kidneys and liver, while the peripheral compartment signifies tissues with lower blood flow, like adipose tissue and muscle tissue.
The...
The...
Three-Compartment Open Model
The three-compartment open model is a pharmacokinetic model used to describe the distribution and elimination of drugs following extravascular administration. It comprises a central compartment representing the plasma and two peripheral compartments. The highly perfused peripheral compartment represents organs and tissues with a rich blood supply, such as the liver, kidneys, and lungs. The scarcely perfused peripheral compartment represents tissues with lower blood supply, such as adipose...


