金属-有机框架六角纳米板:自下而上的合成,拓变化和高效的氧气进化反应
1Henan Province Industrial Technology Research Institute of Resources and Materials, Zhengzhou University, Zhengzhou, Henan 450001, People's Republic of China.
Journal of the American Chemical Society
|April 7, 2020
概括
研究人员使用拓引导方法合成了新的六边形二维金属有机框架 (MOF). 这些MOF被转化为N-化Ni@碳电催化剂,用于高效的氧化演化反应.
科学领域:
- 材料科学
- 纳米技术
- 催化剂
背景情况:
- 二维金属有机框架 (2D MOF) 提供了可调节的性能,用于先进的应用.
- 控制二维MOF的形态对于优化其性能至关重要.
- 以结构拓为指导的自下而上的合成能够精确控制MOF架构.
研究的目的:
- 为新型六边形2DMOF纳米板开发以拓为导向的自下而上的合成.
- 研究胺对MOF形态的影响.
- 从合成的MOF中制造一个N-化Ni@碳电催化剂,用于氧化演化反应.
主要方法:
- 使用扭曲的 (3,4) 连接的 Ni2 ((BDC) 2 ((DABCO) 框架作为模板.
- 采用了包括胺在内的替代抑制过程来调节形态.
- 进行了热解处理,将MOF纳米板转化为N-化Ni@碳电催化剂.
主要成果:
- 成功合成了可控制厚度的六角2DMOF纳米板.
- 从纳米棒到纳米磁盘和纳米板的形态转变.
- 使用N-化Ni@碳催化剂,在10 mA cm-2的氧化演化反应中达到307 mV的低超电位.
结论:
- 以拓为指导的自下而上的合成对于创建具有特定形态的二维MOF是有效的.
- 胺在控制MOF的纳米结构方面发挥着关键作用.
- 由此产生的N-化Ni@碳电催化剂在氧化演变反应中表现出有前途的性能.
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