多形态镜子 分子液体的液体-液体过渡中的多形态
Finlay Walton1, John Bolling1, Andrew Farrell1
1School of Chemistry, University of Glasgow, Glasgow G12 8QQ, U.K.
Journal of the American Chemical Society
|April 7, 2020
概括
液体-液体过渡涉及两个液体状态之间的变化. 这项研究揭示了这些转变与相反的结构相连,
科学领域:
- 物理化学
- 材料科学
- 凝聚物质物理学
背景情况:
- 单元液体中的液体-液体过渡 (LLTs) 是有争议的,通常在超冷状态下观察到.
- 与玻璃化和局部受欢迎的结构有关,但顺序参数仍然未知.
- 了解局部分子包装对于阐明LLT至关重要.
研究的目的:
- 调查分子液体中LLT的潜在原因.
- 确定管理过渡的顺序参数.
- 探索LLT,多态和多态之间的关系.
主要方法:
- 在三酸中实验性研究液体-液体过渡.
- 分析局部分子包装和结构竞争.
- 清晰的液态和玻璃状相的特征.
主要成果:
- 三酸中的LLT来自于模仿两个晶体多态的竞争液体结构.
- 过渡发生在几何挫折液体和动态挫折玻璃之间.
- 证据表明晶体多态和液体多态之间存在普遍联系.
结论:
- 通过与晶体多态性相关的结构竞争推动了LLT.
- 这一发现澄清了LLT的物理基础,并有助于发现新的例子.
- 这项研究促进了对液体无形相态的理解.
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