用于长期储存热能和在0°C以下的光学触发热释放的阿里拉索皮拉
Mihael A Gerkman1, Rosina S L Gibson2, Joaquín Calbo3
1Department of Chemistry, Brandeis University, 415 South Street, Waltham, Massachusetts 02453, United States.
Journal of the American Chemical Society
|April 23, 2020
概括
新型的阿里拉索皮拉衍生物将热能存储在一个转移稳定的液态阶段. 这种储存的热量可以在需要时通过光学触发的结晶,即使在-30°C.
科学领域:
- 材料科学
- 有机化学
- 能量储存
背景情况:
- 阿里拉索皮拉衍生物以其光色特性而闻名.
- 开发高效的热能存储材料对于各种应用至关重要.
研究的目的:
- 研究新型阿里拉索皮拉衍生物的热能储存能力.
- 探索这些化合物的热储和释放机制.
- 为了证明光学触发的结晶控制能量释放.
主要方法:
- 合成四个核心结构和多德卡诺酸功能化的阿里拉佐皮拉衍生物.
- 在超稳定的Z异构体液相中研究热能储存.
- 通过可见光照射和热方法触发的热释放的分析.
- 在各种温度和持续时间下评估Z同位素的稳定性.
主要成果:
- 阿里拉索皮拉衍生物成功地储存了热能在它们的转移稳定的Z异构体液相中.
- 确定了三个不同的热储释放方案 (光学,热,组合).
- 可见光诱导选择性结晶通过Z-to-E异构,释放储存的能量.
- 在没有光学触发的情况下保存了两个多星期的潜在热量.
- 储存了高达92kJ/mol的热能,在0°C以下具有很高的热和液相稳定性.
结论:
- 阿里拉索皮拉衍生物代表了一类用于储存热能的新材料.
- 光学触发的结晶提供了一种精确的控制热释放方法.
- 这些化合物表现出极好的稳定性,使得它们在实际应用中具有前景.
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