优化孔隙空间为柔性-坚固的金属-有机框架以促进痕迹乙去除
Jun Wang1, Yan Zhang1,2, Peixin Zhang1
1School of Resource, Environmental and Chemical Engineering, Nanchang University, Nanchang, Jiangxi 330031, PR China.
Journal of the American Chemical Society
|May 15, 2020
概括
一种基于铜的新型金属有机框架 (MOF) 有效地从乙烯中去除微量乙烯. 这种吸附剂具有很高的选择性和容量,超过了高效气体分离的现有基准.
科学领域:
- 材料科学
- 化学工程
- 纳米技术
背景情况:
- 金属有机框架 (MOF) 对于气体分离至关重要.
- 在工业过程中,有效地从乙烯中去除微量乙至关重要.
- 现有的MOF在选择性和乙烯/乙烯分离能力方面存在局限性.
研究的目的:
- 开发一种灵活坚固的MOF,用于从乙烯中吸附去除微量乙.
- 增强孔隙结构和选择性乙吸附的结合点.
- 与其原型相比,研究一个铜模拟MOF的性能.
主要方法:
- 在MOF设计中采用同质的原理.
- 用铜取代 (II) 来改变孔径.
- 气体异热和单晶结构分析用于吸附验证.
- 通过IAST的选择性计算和突破性实验.
主要成果:
- 铜模拟MOF表现出扩大的孔腔 (3.6 × 4.3 × 4.2 Å3).
- 对C2H2/C2H4实现显著的乙吸收 (4.57 mmol g-1) 和高选择性 (超过两个数量级).
- 与乙烯/乙烯分离的基准MOF相比,已经证明了更好的性能.
- 高乙烯生产率 (14.9 mmol g-1).
结论:
- 基于铜的柔性-坚固的MOF对于从乙烯中吸附去除乙烯具有很高的效率.
- 优化的孔径和结合点是选择性乙吸附的关键.
- 这种MOF为工业气体净化应用提供了有前途的解决方案.
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