通过在水中升级生成紫外线光和具有挑战性的光反应
Björn Pfund1, Debora M Steffen1, Mirjam R Schreier1
1Department of Chemistry, University of Basel, St. Johanns-Ring 19, 4056 Basel, Switzerland.
Journal of the American Chemical Society
|May 16, 2020
概括
研究人员开发了一种新的蓝光驱动的水中的能量转化方法,实现了比以前更高的能量水平. 这一突破使得使用可持续光源的光还原反应具有挑战性.
科学领域:
- 摄影化学
- 可持续的化学
- 材料科学
背景情况:
- 敏感的三倍消灭 (sTTA) 是可见光能量聚合的关键机制.
- 之前的sTTA应用仅限于有机溶剂,能量极限约为3.6 eV.
- 需要在水性介质中建立高效的上转换系统,以实现可持续的应用.
研究的目的:
- 通过使用新型的复合物和纳来证明蓝光驱动的水上转化.
- 为了达到接近4 eV的单元状态能量,以挑战光还原反应.
- 确定使用低功率光源来降低水污染物的可行性.
主要方法:
- 合成量身定制的复合物和纳.
- 在水溶液中实施敏感的三倍三倍灭绝 (sTTA).
- 包括酸键激活和化合物分解的光降解实验.
主要成果:
- 在单元状态能量接近4 eV的水中证明了蓝光驱动的上升转换.
- 实现了具有挑战性的光降解反应,包括化键激活.
- 通过连续波激光和LED光源成功分解了化合物.
结论:
- 这项研究首次证明了水中蓝光转化为紫外线的概念.
- 开发了一种能够高效率地驱动耗能光降低的系统.
- 强调使用低功耗光源的可持续光采集应用的潜力.
相关概念视频
Photoluminescence: Applications
913
Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
913
Photoluminescence: Fluorescence and Phosphorescence
3.2K
Photoluminescence is a process where a molecule absorbs light energy and re-emits it in the form of light. This phenomenon occurs when a substance absorbs photons, promoting its electrons to higher energy level excited states, followed by a relaxation process in which the electrons return to their original ground state energy levels and emit light. Photoluminescence is widely observed in various materials, including semiconductors, and organic and inorganic compounds.
A pair of electrons in a...
A pair of electrons in a...
3.2K
The Z-Scheme of Electron Transport in Photosynthesis
12.7K
The light reactions of photosynthesis assume a linear flow of electrons from water to NADP+. During this process, light energy drives the splitting of water molecules to produce oxygen. However, oxidation of water molecules is a thermodynamically unfavorable reaction and requires a strong oxidizing agent. This is accomplished by the first product of light reactions: oxidized P680 (or P680+), the most powerful oxidizing agent known in biology. The oxidized P680 that acquires an electron from the...
12.7K
Photochemical Electrocyclic Reactions: Stereochemistry
2.1K
The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Selection Rules: Photochemical Activation
2.1K
Ultraviolet and Visible (UV–Vis) Spectroscopy: Overview
4.2K
Ultraviolet–visible (UV–visible or UV–Vis) spectroscopy is an analytical technique that investigates the interaction between matter and UV–Vis light within the electromagnetic spectrum. This method is widely used for its versatility, simplicity, and relatively quick data acquisition, making it valuable for both qualitative and quantitative analysis. When UV–Vis radiation passes through a material, molecules absorb light depending on the energy required for...
4.2K
Super-resolution Fluorescence Microscopy
12.1K
Super-resolution fluorescence microscopy (SRFM) provides a better resolution than conventional fluorescence microscopy by reducing the point spread function (PSF). PSF is the light intensity distribution from a point that causes it to appear blurred. Due to PSF, each fluorescing point appears bigger than its actual size, and it is the PSF interference of nearby fluorophores that causes the blurred image. Various approaches to achieving higher resolution through SRFM have recently been...
12.1K


