在Ba5Er2Al2ZrO13中的高质子导电性,六角矿相关的氧化物与内在缺氧层
Taito Murakami1, James R Hester2, Masatomo Yashima1
1Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1-W4-17, O-okayama, Meguro-ku, Tokyo 152-8551, Japan.
Journal of the American Chemical Society
|May 16, 2020
概括
一种新的六角矿相关氧化物,Ba5Er2Al2ZrO13,显示出极好的质子导电性. 这一发现为新型的质子导体在能源应用中开辟了道路.
科学领域:
- 材料科学
- 固态化学
- 电化学
背景情况:
- 电解质中的质子导电性对于燃料电池等电化学装置至关重要.
- 现有的质子导体仅限于特定的结构家族,例如立方矿.
- 在中间温度 (300-600°C) 需要高质子导电性.
研究的目的:
- 识别和描述一种新型的质子导体.
- 探索六角矿相关的氧化物以提高质子导电性.
- 了解新材料中的质子传输机制.
主要方法:
- Ba5Er2Al2ZrO13的合成和表征
- 用瑞特维尔德分析进行中子衍射.
- 基于债券价值的能量计算.
- 热重力测量分析 (TGA)
主要成果:
- 合成了与矿相关的六角氧化物Ba5Er2Al2ZrO13.
- 在300°C和1200°C之间观察到超过10^-3 S cm^-1的质子导电性.
- 中子衍射和计算证实了缺氧h'层中的质子结合.
结论:
- Ba5Er2Al2ZrO13代表了一个新的质子导体结构家族.
- 缺氧的h'层是质子运输的关键.
- 这一发现为基于六角矿相关氧化物设计先进的质子导体提供了策略.
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