在SAPO-37和HY上支持的同结构原子分散催化剂
Jorge E Perez-Aguilar1, Cong-Yan Chen1,2, James T Hughes3
1Department of Chemical Engineering, University of California, Davis, California 95616, United States.
Journal of the American Chemical Society
|June 5, 2020
概括
氨酸 (SAPOs) 是原子分散催化剂的有效支持物. SAPO-37支持,使得选择性乙烯化和增强稳定性相比岩支持.
科学领域:
- 不同质的催化
- 材料科学
- 纳米技术
背景情况:
- 石是金属催化剂的常见支物.
- 氨酸 (SAPOs) 在结构上相似,但作为催化剂支剂的探索较少.
- 原子分散的金属具有独特的催化性能.
研究的目的:
- 调查SAPO-37作为原子分散的支持.
- 为了比较SAPO支持的与酸支持的的催化性能.
- 了解支材料对催化活性,选择性和稳定性的影响.
主要方法:
- 在SAPO-37上合成原子分散的复合物.
- 使用红外 (IR) 和扩展X射线吸收细结构 (EXAFS) 光谱进行表征.
- 在化和二聚化条件下进行乙烯转化催化试验.
主要成果:
- 通过两个Rh-O键在框架站点成功定到SAPO-37上.
- 形成了统一的,明确的支持物种,由尖的红外波段证实.
- SAPO-37支持罗选择性催化乙烯化,并且表现出高于酸支持的稳定性.
结论:
- SAPO-37是原子分散金属催化剂的一个有前途的支持.
- 支持的选择对催化选择性和稳定性产生重大影响.
- 这项研究为使用同结构材料的催化研究提供了一个平台.
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