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Updated: Dec 17, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

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通过[Co13C2的快速质子转移和进化反应

Cody R Carr1, Atefeh Taheri1, Louise A Berben1

  • 1Department of Chemistry, University of California at Davis, Davis, California 95616, United States.

Journal of the American Chemical Society
|June 24, 2020
PubMed
概括

这项研究引入了一种碳聚合催化剂,可显著加速质子转移 (PT) 和电子转移 (ET) 反应. 它具有独特的电子结构,可实现扩散限制的反应速度,优于传统方法.

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¹³C NMR: ¹H–¹³C Decoupling

The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
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