用结合的有机框架作为功能材料的调节平台
Bin Wang1,2, Rui-Biao Lin2, Zhangjing Zhang1
1Fujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, 32 Shangsan Road, Fuzhou 350007, P.R. China.
用键构建的有机框架 (HOF) 是使用键构建的新型多孔材料. 它们的独特特性使其在分离,传感和催化等方面具有多样性的应用.
科学领域:
- 材料科学
- 超分子化学
背景情况:
- 结合有机框架 (HOF) 是新兴的多孔晶体材料.
- 它们通过键自组,与MOF和COF不同.
- 由于较弱的H键,HOF具有独特的特性,如温和的合成和可加工性.
研究的目的:
- 审查在构建多孔HOF中使用的H结合图案.
- 突出这些HOF的多样化应用.
主要方法:
- 精心挑选的键图案.
- 使用其他弱相互作用,如 π-π 堆叠和范德瓦尔斯力.
- 框架互透战略.
主要成果:
- 构建各种多孔的HOF.
- 对于功能性材料的HOF调节平台的演示.
- 确定关键的H结合模式及其在框架组装中的作用.
结论:
- 钢是一种具有独特特性的多功能材料.
- 它们的应用范围包括气体分离,奇拉分离,传感,催化等.
- 对于高级功能材料的开发,HOF具有显著的潜力.
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