在多价离子的存在下,Zwitterionic瓶聚合物的超性
Vahid Adibnia1,2, Mateusz Olszewski3, Gregory De Crescenzo2
1Faculty of Pharmacy, Université de Montréal, 2900 Édouard-Montpetit, Montreal, Quebec H3C 3J7, Canada.
Journal of the American Chemical Society
|August 14, 2020
概括
这种聚合物具有优异的滑性,即使存在多价离子,也保持低摩擦. 这种性能超过了多电解质刷,显示了对离子诱导的降解的弹性.
科学领域:
- 表面科学和三角学
- 聚合物化学和材料科学
背景情况:
- 在多价离子的存在下,多电解质刷经常显示滑率降低.
- 了解在离子影响下被物理吸收的聚合物的行为对于先进的材料应用至关重要.
研究的目的:
- 为了研究物理吸收的zwitterionic瓶聚合物的滑特性.
- 与多电解质刷相比,评估它们在多价离子存在时的性能.
主要方法:
- 使用表面力装置 (SFA) 来测量摩擦和滑.
- 在不同正常负荷和多价离子度下测试的基聚合物.
主要成果:
- 即使在0.1mM的多价离子度下,Zwitterionic瓶聚合物也保持了低的摩擦系数 (∼10-3).
- 由离子桥接和脱水引发的表面磨损只发生在高的正常负荷下.
- 部分聚合物脱落不会影响滑性能.
结论:
- 在多价离子的存在下,物理吸收的zwitterionic瓶聚合物表现出异常的滑性能.
- 在相似的离子条件下,它们的性能优于共接种的多电解质刷.
- 对于具有多价离子的环境,Zwitterionic刷提供强大的滑解决方案.
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