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开放和封闭的激素:在未配对电子周围的局部几何学规则 魔力旋转角度 动态核极化性能

Gabriele Stevanato1, Gilles Casano2, Dominik J Kubicki1

  • 1Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), CH-1015 Lausanne, Switzerland.

Journal of the American Chemical Society
|August 19, 2020
PubMed
概括

研究人员发现了一种新的设计原理,用于在神奇角度旋转动态核极化 (MAS DNP) 中的极化剂 (PA). 局部电子几何学显著影响DNP增强,从而提高敏感材料分析的新PA设计的性能.

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