在脱过程中实现耐焦铁催化剂
Zhiyuan Yang1,2, Huan Li3, Hang Zhou1
1Key Lab of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China.
Journal of the American Chemical Society
|September 1, 2020
概括
在MFI热中大量存在的铁催化剂为从页岩气中生产轻型烯酸提供了可持续的解决方案. 这种新型催化剂表现出极高的耐焦性和高选择性,超越了贵金属催化剂的局限性.
科学领域:
- 催化剂
- 材料科学
- 化学工程
背景情况:
- 非氧化脱是从页岩气中生产轻型烯的关键过程.
- 目前的催化剂通常依赖于贵金属 (如白金) 或有毒元素 (如),并遭受焦炭形成,导致失活.
- 开发丰富,稳定和高效的催化剂对于可持续的烯酸生产至关重要.
研究的目的:
- 开发一种新型的催化剂,使用地球上丰富的铁来非氧化脱乙.
- 提高催化剂的稳定性和抗焦形成.
- 为了实现轻型烯酸生产的高活性和选择性
主要方法:
- 使用乙烯基二胺四酸合成含铁的MFI化 (FeS-1-EDTA).
- 乙脱的催化试验
- 广泛的表征 (例如,光谱,显微镜) 和密度函数理论 (DFT) 的计算.
主要成果:
- 合成的FeS-1-EDTA催化剂在200小时的运行中表现出优越的焦炭耐受性.
- 达到高活性和选择性 (26.3%的转化率,>97.5%的乙烯选择性在873K),接近热力学平衡.
- 鉴定证实了岩结构中的均隔离和稳定的Fe位点.
结论:
- 在MFI焦岩中均分离的Fe位点增强了乙脱和产品脱.
- FeS-1-EDTA催化剂有效地阻碍了焦炭的形成,提供了稳定和高效的替代品.
- 这种土壤丰富的铁催化剂是从页岩气中生产轻型烯酸的有希望的可持续途径.
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