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Updated: Dec 9, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
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Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

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在PIII/PV合成循环中循环氧化添加,连接物转化和减少消除

Soohyun Lim1, Alexander T Radosevich1

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, United States.

Journal of the American Chemical Society
|September 10, 2020
PubMed
概括

这项研究引入了使用新型三胺的合成循环来替代C-F键. 该循环涉及氧化添加,配体转化和还原性消除,表明主要组位点的关键机械步骤.

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