运行NMC811/石墨离子电池的NMR:结构,动力学和金属沉积
Katharina Märker1,2, Chao Xu1,2, Clare P Grey1,2
1Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom.
Journal of the American Chemical Society
|September 22, 2020
概括
核磁共振 (NMR) 光谱可以监测离子电池 (LIB) 的性能和降解. 这项技术揭示了离子流动性和金属沉积的洞察力,这对于改善电池寿命和安全至关重要.
科学领域:
- 材料科学
- 电化学
- 分析化学
背景情况:
- 离子电池对现代社会至关重要,但寿命有限.
- 了解电池降解机制对于提高性能和安全至关重要.
- 运行分析技术对于研究电池在运行过程中的动态过程是非常宝贵的.
研究的目的:
- 为了证明核磁共振 (NMR) 光谱对完全LIB细胞的适用性.
- 使用NMR研究高能LIB的循环性能和降解机制.
- 了解不同条件下的离子流动性和金属沉积.
主要方法:
- 在行业标准的LiNi0.8Mn0.1Co0.1O2 (NMC811) /石墨全细胞上使用Li NMR光谱.
- 在实用的速度和不同温度进行实验以模拟现实世界的电池使用情况.
- 同时监测阴极和阳极电极中的过程.
主要成果:
- 在操作条件下证明NMC811/石墨电池的实际循环性能.
- 在两个电极中观察到离子的移动性及其温度依赖性.
- 在低温下检测到石墨阳极上的金属沉积,
结论:
- 核磁共振光谱是研究完全LIB的强大工具.
- 这项技术为离子动力学和金属等降解机制提供了独特的洞察力.
- 这些发现有助于更好地了解LIB的性能限制和安全风险.
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