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- 对称的迪尼克尔催化剂对抗选择性 [4 + 1] - 循环添加剂

Michael J Behlen1, Christopher Uyeda1

  • 1Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.

Journal of the American Chemical Society
|September 25, 2020
PubMed
概括

迪尼克尔催化剂使不对称的 [4 + 1] 环添加成为可能,产生具有高Z-选择性的甲基烯cyclopentenes. 这种方法是立体融合的,允许混合E/Z-dienes以实现高效的合成.

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