由凝纳米粒子相变驱动的热电池
Benshuai Guo1, Yu Hoshino1, Fan Gao2
1Department of Chemical Engineering, Graduate School of Engineering, Kyushu University, Motooka 744, Nishi-ku, Fukuoka 819-0395, Japan.
Journal of the American Chemical Society
|September 28, 2020
概括
使用水凝纳米粒子的热电转换为产生清洁能源提供了一种新方式. 这些新型热电池有效地将低温热转化为电力,为可持续的电力解决方案铺平了道路.
科学领域:
- 材料科学
- 电化学
- 能源转换
背景情况:
- 热电转换对于物联网和无碳社会至关重要.
- 低温热源是众多的, 但很难有效地利用.
- 热电池提供低成本,灵活的热电转换方法,但需要提高效率.
研究的目的:
- 使用水凝纳米粒子开发高效的热电转换.
- 探索水凝体积相位转换对能量采集的潜力.
- 创造一种可持续的,无毒的,廉价的能源.
主要方法:
- 采用聚N-异烯胺纳米颗粒的输热驱动体积相转换 (VPT).
- 在生理温度周围通过VPT生成pH梯度.
- 使用在电极上的化的质子合电子转移 (PCET) 反应.
主要成果:
- 达到高达0.049和0.053的pH梯度.
- 获得了高Seebeck系数 (S) 的 -6.7 和 +6.1 mV K-1.
- 由水凝相转换驱动的有效热电转换.
结论:
- 水凝纳米粒子VPT可以驱动高效的热电转换.
- 这些热电池提供了一种灵活,无毒,廉价的无碳能源采集方法.
- 潜在的应用包括使用太阳能,身体或废热的充电设备.
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