使用双界面工程方法提高混合矩阵膜的气体分离选择性
Chunhui Wu1, Kexin Zhang1, Hongliang Wang1
1School of Physical Science and Technology, ShanghaiTech University, Shanghai, China 201210.
Journal of the American Chemical Society
|October 14, 2020
概括
使用金属有机框架 (MOF) 的新型双界面工程方法提高了MOF-聚合物兼容性. 这种方法显著提高了CO2/CH4和乙烯/乙应用的混合矩阵膜的气体分离性能.
科学领域:
- 材料科学
- 化学工程
- 分离科学
背景情况:
- 混合矩阵膜 (MMM) 对于气体分离至关重要.
- MOF与聚合物之间的界面兼容是一个重大挑战.
- 现有的MOF-聚合物接口往往限制了膜性能.
研究的目的:
- 开发MOF聚合物MMM的双界面工程策略.
- 提高接口兼容性和提高气体分离性能.
- 研究MOF-74外对膜选择性和透性的影响.
主要方法:
- 作为过渡阶段使用了20nm多晶MOF-74外.
- MOF-74外将MOF-聚合物接口设计成MOF-MOF和MOF-聚合物接口.
- 该方法应用于基于UiO-66-NH2和MOF-801的MMM.
主要成果:
- MOF-74外增加了300%的聚合物相互作用,确保了良好的界面兼容性.
- UiO-66-NH2 MMM 显示了同时增加的 CO2/CH4 选择性和 CO2 透性.
- 通过"气体聚焦"机制,MOF-801 MMM 的乙烯/乙选择性提高了76%.
结论:
- 双界面工程方法有效地解决了MOF聚合物界面问题.
- 这种策略导致高性能MMM用于具有挑战性的气体分离.
- 开发的膜显示了气体净化工业应用的潜力.
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