矿的深度非生物风化
Xin Gu1, Peter J Heaney2, Fabio D A Aarão Reis3
1Department of Geosciences, The Pennsylvania State University, University Park, PA 16802, USA. xug102@psu.edu.
概括
页岩中的氧化是由氧气扩散,侵蚀和裂变控制的,而不是微生物. 这些因素限制了对地球的影响.
科学领域:
- 地质化学
- 环境科学
- 矿物学
背景情况:
- 铁硫化物是一种常见的矿物质,容易被氧化.
- 自从地球的早期大气层富含氧气以来, 矿在沉积物中一直很稀缺.
- 页岩是最常见的表面岩石,是气候变化研究的关键地点.
研究的目的:
- 确定控制页岩气候变化的氧化因素.
- 分析从纳米到米的多个尺度上的化物.
- 评估微生物在全球化中的作用.
主要方法:
- 页岩气候变化的多尺度分析 (10^-9到10^2米).
- 研究矿物反应的化学分析.
- 微观分析以检查物理结构和过程.
主要成果:
- 在当前的大气条件下,氧气扩散到矿物表面限制了矿的氧化.
- 大规模侵蚀和裂变是关键的调节因素.
- 铁或硫的微生物氧化不能控制全球化流.
结论:
- 矿的反应性主要由裂变和侵蚀等物理过程以及氧气的可用性决定.
- 一个多层次的视角对于理解地球的岩气候历史是必不可少的.
- 微生物催化不决定全球的化率.
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