通过无机光热生长制备的Se-Te半结构的路径依赖性形态演化
Kathryn R Hamann1, Azhar I Carim1, Madeline C Meier1
1Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, United States.
Journal of the American Chemical Society
|November 11, 2020
概括
无机光热生长中的新型"历史"效应表明,膜形态取决于先前的光照. 在生长过程中改变光波长会改变纳米结构,表明依赖于路径的进化.
科学领域:
- 材料科学
- 纳米技术
- 摄影化学
背景情况:
- 光热生长是一种物质对光的反应生长的过程.
- 了解薄膜形态对于控制材料属性至关重要.
- 之前的研究还没有充分探讨光热增长中的路径依赖效应.
研究的目的:
- 为了调查路径依赖
- 历史
- 在- (Se-Te) 薄膜的两步无机光热增长中产生作用.
- 阐明光学刺激史对电影形态和特征的作用.
- 分析驱动这种观察路径依赖的潜在纳米光子机制.
主要方法:
- 使用受控光波长序列的两步无机光热生长.
- 使用显微镜技术对膜形态的描述.
- 在模拟结构中分析光吸收.
- 经验数据分析以将光学条件与形态结果相关联.
主要成果:
- 一个路径依赖
- 历史
- 其中第二个生长阶段的形态取决于第一阶段的光学条件.
- 短波长的增长跟随着长波长的光线导致了叶片终结和增加的音调.
- 波长顺序的反转导致了线性特征扩展而没有变化.
- 在生长界面的纳米光子过程被确定为不对称路径依赖的原因.
结论:
- 在
- 历史
- 在光热增长中的作用是由新兴的纳米光子过程驱动的.
- 在生长界面上的光场的动态塑造控制了形态演变.
- 这种反循环为精确控制纳米结构形成提供了新的可能性.
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